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Mercurous Sulfate Reference Electrode Hg/Hg2SO4 φ5.75*50mm

SKU: ERS134B

Special Price $120.95

Regular Price: $150.95

Description

• Fits all major brands of potentiostats
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• Size: φ5.75*50mm

In electrochemistry, in order for a specific reaction to occur, a stable electric potential needs to be applied to the working electrode. The potential of the working electrode should always be accurately controlled. This is why a reference electrode is needed as a potential reference standard. Common reference electrodes include Ag/AgCl reference electrode, saturated calomel electrode,Hg/HgO reference electrode, Hg/Hg2SO4 reference electrode and Non aqueous Ag+ reference electrode,etc.

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Product Details

The mercury-mercurous sulfate reference electrode(Hg/Hg2SO4) is mainly used in acidic solutions. This reference electrode is a suitable choice for neutral or acidic systems where it is necessary to avoid chloride ion pollution. It is an electrode composed of metallic mercury, mercurous sulfate and saturated K2SO4 solution, and its electrode potential is 0.652V (25°C).

Specification:
tube diameter: 5.75 mm
effective length: 50 mm
liquid junction core: microporous ceramic filter core
filling solution: Saturated K2SO4
potential stability: <5 mV
operating temperature: 0-40 deg C

Notes:

1.When the mercury sulfate electrode is used, the rubber stopper of the liquid port should be removed first, so that the salt bridge solution can hold a certain flow rate by gravity and the path of the measured solution.

2.There can be no bubbles in the potassium sulfate solution in the electrode to prevent circuit breaking, and a few crystals should be retained in the solution to ensure the saturation of the potassium sulfate solution.

3.When measuring, the salt bridge solution surface of the mercury sulfate electrode should be a certain distance higher than the surface of the measured solution to prevent the measured solution from diffusing to the mercury sulfate electrode.

4.Because the potential of the mercurous sulfate electrode has a large negative temperature coefficient and thermal hysteresis, the temperature fluctuation of the mercury sulfate electrode should be prevented as much as possible during measurement. Accurate measurement should be made by keeping the mercuryous sulfate electrode at a constant temperature.To overcome this shortcoming, a long salt bridge tube is usually added to the lower part of the Hg/Hg2SO4 electrode, so that the Hg/Hg2SO4 electrode is at room temperature, and the temperature of the salt bridge solution is the same as the solution to be tested.

5.If it is found that the measured solution is contaminated with the inside of the mercury sulfate electrode solution, the scale should be scraped off or the inner liquid should be replaced from time to time to maintain accurate measurement.

6.Recommended temperature for electrode: ≤40℃.

7.When the electrode is attached with potassium sulfate solution or crystal, potassium sulfate should be removed at any time.

8.The reference electrode cannot be cleaned under ultrasound.

Different research systems can choose different reference electrodes:
Neutral system------saturated calomel electrode or Ag/AgCl reference electrode
Alkaline system-----Hg/HgO reference electrode
Acidic system-------Hg/Hg2SO4 reference electrode
Non-aqueous system--Non aqueous Ag+ reference electrode

NOTICE:

1.This reference electrode is shorter and can be used in special scenes. Please check the parameters carefully to confirm whether it is suitable for use.

2.Due to shipping safety considerations,all reference electrodes are not filled with solution.Before use,the user needs to prepare an internal solution to fill it into the electrode.

3.Reference electrodes always ship separately.Special shipping arrangements may be required to process your order if you purchase a reference electrode.

4.Additional fees may be applied to cover the costs of shipping the single junction Hg/Hg2SO4 reference electrode.This electrode also may not be available for sale in all countries.

Product Includes:
1 * Hg/Hg2SO4 reference electrode with gold-plated pin
1 * cap
1 * fluorine rubber O-ring

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PRODUCT RELATED

Q.
How to choose ordinary electrochemical cell and sealed electrochemical cell?
A.
Regardless of the user's tightness requirements for the actual test, the sealed electrochemical cell is the first choice. The sealed electrolytic cell is equipped with hollow sealing screws and fluorine rubber O-rings to install and seal the entire device, and then pass inert gas into the cell body to drive out the excess gas inside the cell body to realize the test of the system in an inert environment. If there is no requirement for tightness, no ventilation operation is required. However, if you choose an ordinary electrochemical cell, the related operations of the sealed electrolytic cell cannot be realized.
Q.
What volume of electrochemical cell is suitable to choose?
A.
The volume of the electrolytic cell should be selected moderately. If the volume is too large, the amount of solution will be too much, which is unnecessary. During electrochemical measurement, the electrode surface undergoes oxidation and reduction reactions, and some substances in the solution are reduced by participating in the electrode reaction. At the same time, some reaction products will dissolve into the solution. If the volume of the electrolytic cell is too small, the solution concentration will change significantly during the long-term steady-state measurement, which will eventually affect the experimental results. In most cases, the volume of 50ml and 100ml are more choices.
Q.
How to choose a working electrode?
A.
Common working electrodes include disk electrodes and replaceable electrode holders. The disk electrode is suitable as the base of the modified material, and it is modified to the base area of the disk electrode by mixing a membrane solution or the like with a powdered material. And if the material being studied is a sheet-like structure or the material can be modified to suitable materials such as conductive glass, carbon paper, carbon cloth, etc., it is more practical to choose a replaceable electrode clip.
Q.
How to choose a counter electrode?
A.
One of the important parameters of the counter electrode is its surface area. The counter electrode must have a large enough area to support the current conduction generated on the working electrode. Generally, the area of the counter electrode is 3-5 times the area of the working electrode. When choosing a disk electrode as the working electrode, platinum wire electrode is a good choice. When choosing sheet materials as working electrodes, platinum wire ring electrodes and platinum sheet electrodes are good choices.
Q.
How to choose a reference electrode?
A.
Generally speaking, calomel electrode or Ag/AgCl reference electrode is used in neutral system. Since the potential of calomel electrode changes greatly with temperature, when the temperature exceeds 70 degrees, it needs to be used with a salt bridge or replaced Use Ag/AgCl reference electrode. Hg2SO4 reference electrodes are generally suitable for sulfuric acid or sulfate systems. Hg/HgO reference electrodes are generally suitable for alkaline electrolyte solutions, of which the strong alkali system also needs to be used with a salt bridge, and the filling liquid in the salt bridge is consistent with the filling liquid of the reference electrode. The non-aqueous organic system needs to use a Ag/Ag+ reference electrode. When using a non-aqueous Ag/Ag+ reference electrode, the user needs to prepare a solution containing supporting electrolyte and silver ions (usually 10mM) and inject it into the reference electrode chamber. Due to shipping safety considerations, all reference electrodes are not filled with solution. Before use, the user needs to prepare an internal solution to fill it into the electrode.
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